Effect of Native Oxide Film on Commercial Magnesium Alloys Substrates and Carbonate Conversion Coating Growth and Corrosion Resistance

نویسندگان

  • Sebastián Feliu
  • Alejandro Samaniego
  • Elkin Alejandro Bermudez
  • Amir Abdelsami El-Hadad
  • Irene Llorente
  • Juan Carlos Galván
چکیده

Possible relations between the native oxide film formed spontaneously on the AZ31 and AZ61 magnesium alloy substrates with different surface finish, the chemistry of the outer surface of the conversion coatings that grows after their subsequent immersion on saturated aqueous NaHCO₃ solution treatment and the enhancement of corrosion resistance have been studied. The significant increase in the amount of aluminum and carbonate compounds on the surface of the conversion coating formed on the AZ61 substrate in polished condition seems to improve the corrosion resistance in low chloride ion concentration solutions. In contrast, the conversion coatings formed on the AZ31 substrates in polished condition has little effect on their protective properties compared to the respective as-received surface.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Characterization of Oxide Film Formed on Ck45 Steel by Plasma Electrolytic Oxidation Method

Plasma electrolytic oxidation (PEO) is the new, environmentally and cost-effective method for coating the metals. This method vastly has been studied for coating Aluminum, Titanium and Magnesium and their alloys and recently for steel. In present study, Ck45 steel samples were coated by PEO method in order to improve corrosion resistance. During this process specimens were immerged in carbonate...

متن کامل

Native Air-Formed Oxide Film and its Effect on Magnesium Alloys Corrosion

The present work uses X-ray photoelectron spectroscopy (XPS) analysis to compare the chemical composition of native oxide films formed spontaneously on commercial pure magnesium and AZ31, AZ80 and AZ91D magnesium alloys. The study considers both the outer surface and inner regions of the films with the assistance of argon ion bombardment. Possible relationships are established between the alloy...

متن کامل

Phenolic Modified Ceramic Coating on Biodegradable Mg Alloy: The Improved Corrosion Resistance and Osteoblast-Like Cell Activity

Magnesium alloys have great potential for developing orthopedic implants due to their biodegradability and mechanical properties, but the rapid corrosion rate of the currently-available alloys limits their clinical applications. To increase the corrosion resistance of the substrate, a protective ceramic coating is constructed by a micro-arc oxidation (MAO) process on ZK60 magnesium alloy. The p...

متن کامل

Effect of Tricalcium Magnesium Silicate Coating on the Electrochemical and Biological Behavior of Ti-6Al-4V Alloys

In the current study, a sol-gel-synthesized tricalcium magnesium silicate powder was coated on Ti-6Al-4V alloys using plasma spray method. Composition of feed powder was evaluated by X-ray diffraction technique before and after the coating process. Scanning electron microscopy and atomic force microscopy were used to study the morphology of coated substrates. The corrosion behaviors of bare and...

متن کامل

Correlation between the surface chemistry and the atmospheric corrosion of AZ31, AZ80 and AZ91D magnesium alloys

* Corresponding author. Tel: 34 1 3944348; Fax: 34 1 3944357 E-mail: [email protected] ABSTRACT X-ray photoelectron spectroscopy (XPS) was used in order to investigate the correlation between the surface chemistry and the atmospheric corrosion of AZ31, AZ80 and AZ91D magnesium alloys exposed to 98% relative humidity at 50oC. Commercially pure magnesium, used as the reference material, reveale...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 7  شماره 

صفحات  -

تاریخ انتشار 2014